The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was a collection of heuristic prescriptions which are now understood to be the first quantum corrections to classical mechanics. The Bohr model was the focus of study, and Arnold Sommerfeld made a crucial contribution by quantizing the z-component of the angular momentum, which in the old quantum era was inappropriately called space quantization (Richtungsquantelung). This allowed the orbits of the electron to be ellipses instead of circles, and introduced the concept of quantum degeneracy. The theory would have correctly explained the Zeeman effect, except for the issue of electron spin.
The main tool was Bohr–Sommerfeld quantization, a procedure for selecting out certain discrete set of states of a classical integrable motion as allowed states. These are like the allowed orbits of the Bohr model of the atom; the system can only be in one of these states and not in any states in between. The theory did not extend to chaotic motions, because it required a full multiply periodic trajectory of the classical system for all time in order to pose the quantum conditions.
Read more about Old Quantum Theory: Basic Principles, De Broglie Waves, Kramers Transition Matrix, Limitations of The Old Quantum Theory, History
Famous quotes containing the words quantum theory, quantum and/or theory:
“But how is one to make a scientist understand that there is something unalterably deranged about differential calculus, quantum theory, or the obscene and so inanely liturgical ordeals of the precession of the equinoxes.”
—Antonin Artaud (1896–1948)
“But how is one to make a scientist understand that there is something unalterably deranged about differential calculus, quantum theory, or the obscene and so inanely liturgical ordeals of the precession of the equinoxes.”
—Antonin Artaud (1896–1948)
“There never comes a point where a theory can be said to be true. The most that one can claim for any theory is that it has shared the successes of all its rivals and that it has passed at least one test which they have failed.”
—A.J. (Alfred Jules)