Design of Liquid Crystalline Materials
A very large number of chemical compounds are known to exhibit one or several liquid crystalline phases. Despite significant differences in chemical composition, these molecules have some common features in chemical and physical properties. There are two types of thermotropic liquid crystals: discotics and rod-shaped molecules. Discotics are flat disc-like molecules consisting of a core of adjacent aromatic rings. This allows for two dimensional columnar ordering. Rod-shaped molecules have an elongated, anisotropic geometry which allows for preferential alignment along one spatial direction.
• The molecular shape should be relatively thin or flat, especially within rigid molecular frameworks.
• The molecular length should be at least 1.3 nm, consistent with the presence of long alkyl group on many room-temperature liquid crystals.
• The structure should not be branched or angular.
• A low melting point is preferable in order to avoid metastable, monotropic liquid crystalline phases. Low-temperature mesomorphic behavior in general is technologically more useful, and alkyl terminal groups promote this.
An extended, structurally rigid, highly anisotropic shape seems to be the main criterion for liquid crystalline behavior, and as a result many liquid crystalline materials are based on benzene rings.
Read more about this topic: Liquid Crystal
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