Solid - Classes of Solids - Nanomaterials

Nanomaterials

Many traditional solids exhibit different properties when they shrink to nanometer sizes. For example, nanoparticles of usually yellow gold and gray silicon are red in color; gold nanoparticles melt at much lower temperatures (~300 °C for 2.5 nm size) than the gold slabs (1064 °C); and metallic nanowires are much stronger than the corresponding bulk metals. The high surface area of nanoparticles makes them extremely attractive for certain applications in the field of energy. For example, platinum metals may be provide improvements as automotive fuel catalysts, as well as proton exchange membrane (PEM) fuel cells. Also, ceramic oxides (or cermets) of lanthanum, cerium, manganese and nickel are now being developed as solid oxide fuel cells (SOFC). Lithium, lithium–titanate and tantalum nanoparticles are being applied in lithium ion batteries. Silicon nanoparticles have been shown to dramatically expand the storage capacity of lithium ion batteries during the expansion/contraction cycle. Silicon nanowires cycle without significant degradation and present the potential for use in batteries with greatly expanded storage times. Silicon nanoparticles are also being used in new forms of solar energy cells. Thin film deposition of silicon quantum dots on the polycrystalline silicon substrate of a photovoltaic (solar) cell increases voltage output as much as 60% by fluorescing the incoming light prior to capture. Here again, surface area of the nanoparticles (and thin films) plays a critical role in maximizing the amount of absorbed radiation.