Theory
The basic ideas behind transition state theory are as follows:
- Rates of reaction can be studied by examining activated complexes which lie near the saddle point of a potential energy surface. The details of how these complexes are formed are not important. The saddle point itself is called the transition state.
- The activated complexes are in a special equilibrium (quasi-equilibrium) with the reactant molecules.
- The activated complexes can convert into products, and kinetic theory can be used to calculate the rate of this conversion.
Read more about this topic: Transition State Theory
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