Internal Energy of A Closed Thermodynamic System
This above summation of all components of change in internal energy assume that a positive energy denotes heat added to the system or work done on the system, while a negative energy denotes work of the system on the environment.
Typically this relationship is expressed in infinitesimal terms using the differentials of each term. Only the internal energy is an exact differential. For a system undergoing only thermodynamics processes, i.e. a closed system that can exchange only heat and work, the change in the internal energy is
which constitutes the first law of thermodynamics. It may be expressed in terms of other thermodynamic parameters. Each term is composed of an intensive variable (a generalized force) and its conjugate infinitesimal extensive variable (a generalized displacement).
For example, for a non-viscous fluid, the mechanical work done on the system may be related to the pressure p and volume V. The pressure is the intensive generalized force, while the volume is the extensive generalized displacement:
- .
This defines the direction of work, W, to be energy flow from the working system to the surroundings, indicated by a negative term. Taking the direction of heat transfer Q to be into the working fluid and assuming a reversible process, the heat is
- .
- is temperature
- is entropy
and the change in internal energy becomes
Read more about this topic: Internal Energy
Famous quotes containing the words internal, energy, closed and/or system:
“The internal effects of a mutable policy ... poisons the blessings of liberty itself.”
—James Madison (1751–1836)
“A government deriving its energy from the will of the society, and operating, by the reason of its measures, on the understanding and interest of the society ... is the government for which philosophy has been searching and humanity been fighting from the most remote ages ... which it is the glory of America to have invented, and her unrivalled happiness to possess.”
—James Madison (1751–1836)
“No domain of nature is quite closed to man at all times.”
—Henry David Thoreau (1817–1862)
“Science is a system of statements based on direct experience, and controlled by experimental verification. Verification in science is not, however, of single statements but of the entire system or a sub-system of such statements.”
—Rudolf Carnap (1891–1970)