Intensive and Extensive Properties - Extensive Properties

Extensive Properties

An extensive property is defined by the IUPAC Green Book as a physical quantity which is the sum of the properties of separate noninteracting subsystems that compose the entire system. The value of such an additive property is proportional to the size of the system it describes, or to the quantity of matter in the system. In melting ice, the amount of heat required to melt ice is an extensive property. The amount of heat required to melt one ice cube would be much less than the amount of heat required to melt an iceberg, so it is dependent on the quantity.

Extensive properties are the counterparts of intensive properties, which are intrinsic to a particular subsystem. Dividing one type of extensive property by a different type of extensive property will in general give an intensive value. For example, mass (extensive) divided by volume (extensive) gives density (intensive).

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