Structure
The most common form of crystalline alumina is known as corundum. The oxygen ions nearly form a hexagonal close-packed structure with aluminium ions filling two-thirds of the octahedral interstices. Each Al3+ center is octahedral. In terms of its crystallography, corundum adopts a trigonal Bravais lattice with a space group of R-3c (number 167 in the International Tables). The primitive cell contains two formula units of aluminium oxide.
Alumina also exists in other phases, namely γ-, δ-, η-, θ-, and χ-aluminas. Each has a unique crystal structure and properties. The so-called β-alumina proved to be NaAl11O17.
Read more about this topic: Aluminium Oxide
Famous quotes containing the word structure:
“When a house is tottering to its fall,
The strain lies heaviest on the weakest part,
One tiny crack throughout the structure spreads,
And its own weight soon brings it toppling down.”
—Ovid (Publius Ovidius Naso)
“In the extent and proper structure of the Union, therefore, we behold a republican remedy for the diseases most incident to republican government.”
—James Madison (1751–1836)
“I really do inhabit a system in which words are capable of shaking the entire structure of government, where words can prove mightier than ten military divisions.”
—Václav Havel (b. 1936)