Specific Carbocations
Cyclopropylcarbinyl cations can be studied by NMR:
In the NMR spectrum of a dimethyl derivative, two nonequivalent signals are found for the two methyl groups indicating that the molecular conformation of this cation not perpendicular (as in A) but is bisected (as in B) with the empty p-orbital and the cyclopropyl ring system in the same plane:
In terms of bent bond theory, this preference is explained by assuming favorable orbital overlap between the filled cyclopropane bent bonds and the empty p-orbital.
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