Safety Considerations
Zinc chloride is a skin and respiratory irritant according to its MSDS. Precautions that apply to anhydrous ZnCl2 are those applicable to other anhydrous metal halides, i.e. hydrolysis can be exothermic and contact should be avoided. Concentrated solutions are acidic and corrosive and specifically attack cellulose and silk as Lewis acids.
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“For hours, in fall days, I watched the ducks cunningly tack and veer and hold the middle of the pond, far from the sportsman;... but what beside safety they got by sailing in the middle of Walden I do not know, unless they love its water for the same reason that I do.”
—Henry David Thoreau (1817–1862)
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