Performance
A typical, well-designed ammonium perchlorate composite propellant (APCP) first stage motor may have a vacuum specific impulse (Isp) as high as 285.6 seconds (Titan IVB SRMU). This compares to 339.3 s for kerosene/liquid oxygen (RD-180) and 452.3 s for hydrogen/oxygen (Block II SSME) bipropellant engines. Upper stage specific impulses are somewhat greater: as much as 303.8 s for APCP (Orbus 6E), 359 s for kerosene/oxygen (RD-0124) and 465.5 s for hydrogen/oxygen (RL10B-2). Propellant fractions are usually somewhat higher for (non-segmented) solid propellant first stages than for upper stages. The 117,000 pound Castor 120 first stage has a propellant mass fraction of 92.23% while the 31,000 pound Castor 30 upper stage recently developed for Orbital Science's Taurus II COTS (International Space Station resupply) launch vehicle has a 91.3% propellant fraction with 2.9% graphite epoxy motor casing, 2.4% nozzle, igniter and thrust vector actuator, and 3.4% non-motor hardware including such things as payload mount, interstage adapter, cable raceway, instrumentation, etc. Castor 120 and Castor 30 are 93 and 92 inches in diameter, respectively, and serve as stages on the Athena IC and IIC commercial launch vehicles. A four stage Athena II using Castor 120s as both first and second stages became the first commercially developed launch vehicle to launch a lunar probe (Lunar Prospector) in 1998.
Solid rockets can provide high thrust for relatively low cost. For this reason, solids have been used as initial stages in rockets (the classic example being the Space Shuttle), while reserving high specific impulse engines, especially less massive hydrogen fueled engines for higher stages. In addition, solid rockets have a long history as the final boost stage for satellites due to their simplicity, reliability, compactness and reasonably high mass fraction. A spin-stabilized solid rocket motor is sometimes added when extra velocity is required, such as for a mission to a comet or the outer solar system, because a spinner does not require a guidance system (on the newly added stage). Thiokol's extensive family of mostly titanium-cased Star space motors has been widely used, especially on Delta launch vehicles and as spin-stabilized upper stages to launch satellites from the cargo bay of the Space Shuttle. Star motors have propellant fractions as high as 94.6% but add-on structures and equipment reduce the operating mass fraction by 2% or more.
Higher performing solid rocket propellants are used in large strategic missiles (as opposed to commercial launch vehicles). HMX, C4H8N4(NO2)4, a nitramine with greater energy than ammonium perchlorate, was used in the propellant of the Peacekeeper ICBM and is the main ingredient in NEPE-75 propellant used in the Trident II D-5 Fleet Ballistic Missile. It is because of explosive hazard that the higher energy military solid propellants containing HMX are not used in commercial launch vehicles except when the LV is an adapted ballistic missile already containing HMX propellant (Minotaur IV and V based on the retired Peacekeeper ICBMs). The Naval Air Weapons Station at China Lake, CA developed a new compound, C6H6N6(NO2)6, called simply CL-20 (China Lake compound #20). Compared to HMX, CL-20 has 14% more energy per mass, 20% more energy per volume, and a higher oxygen-to-fuel ratio. One of the motivations for development of these very high energy density military solid propellants is to achieve mid-course exo-atmospheric ABM capability from missiles small enough to fit in existing ship-based below-deck vertical launch tubes and air-mobile truck-mounted launch tubes. CL-20 propellant compliant with Congress' 2004 insensitive munitions (IM) law has been demonstrated and may, as its cost comes down, be suitable for use in commercial launch vehicles, with a very significant increase in performance compared with the currently favored APCP solid propellants. With a specific impulse of 309 s already demonstrated by Peacekeeper's second stage using HMX propellant, the higher energy of CL-20 propellant can be expected to increase specific impulse to around 320 s in similar ICBM or launch vehicle upper stage applications, without the explosive hazard of HMX.
An attractive attribute for military use is the ability for solid rocket propellant to remain loaded in the rocket for long durations and then reliably launched at a moment's notice.
Read more about this topic: Solid-fuel Rocket
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