Total Internal Reflection and Critical Angle
When light travels from a medium with a higher refractive index to one with a lower refractive index, Snell's law seems to require in some cases (whenever the angle of incidence is large enough) that the sine of the angle of refraction be greater than one. This of course is impossible, and the light in such cases is completely reflected by the boundary, a phenomenon known as total internal reflection. The largest possible angle of incidence which still results in a refracted ray is called the critical angle; in this case the refracted ray travels along the boundary between the two media.
For example, consider a ray of light moving from water to air with an angle of incidence of 50°. The refractive indices of water and air are approximately 1.333 and 1, respectively, so Snell's law gives us the relation
which is impossible to satisfy. The critical angle θcrit is the value of θ1 for which θ2 equals 90°:
Read more about this topic: Snell's Law
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