Composition and Color
Shales are typically composed of variable amounts of clay minerals and quartz grains and the typical color is gray. Addition of variable amounts of minor constituents alters the color of the rock. Black shale results from the presence of greater than one percent carbonaceous material and indicates a reducing environment. Black shale can also be referred to as black metal. Red, brown and green colors are indicative of ferric oxide (hematite – reds), iron hydroxide (goethite – browns and limonite – yellow), or micaceous minerals (chlorite, biotite and illite – greens).
Clays are the major constituent of shales and other mudrocks. The clay minerals represented are largely kaolinite, montmorillonite and illite. Clay minerals of Late Tertiary mudstones are expandable smectites whereas in older rocks especially in mid to early Paleozoic shales illites predominate. The transformation of smectite to illite produces silica, sodium, calcium, magnesium, iron and water. These released elements form authigenic quartz, chert, calcite, dolomite, ankerite, hematite and albite, all trace to minor (except quartz) minerals found in shales and other mudrocks.
Shales and mudrocks contain roughly 95 percent of the organic matter in all sedimentary rocks. However, this amounts to less than one percent by mass in an average shale. Black shales which form in anoxic conditions contain reduced free carbon along with ferrous iron (Fe2+) and sulfide (S2-). Pyrite and amorphous iron sulfide along with carbon produce the black and purple coloration.
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