Former Captains
| Player | # | Seasons | Captaincy |
|---|---|---|---|
| Ola Toivonen | 7 | 2009– | 2011-12 |
| Orlando Engelaar | 8 | 2009– | 2011 |
| Ibrahim Afellay | 20 | 2003–10 | 2010 |
| Timmy Simons | 6 | 2005–10 | 2007–10 |
| Phillip Cocu | 8 | 1995–98, 2004–07 | 2005–07 |
| Mark van Bommel | 6 | 1999–05, 2012- | 2000–05, 2012- |
| Luc Nilis | 10 | 1994–00 | 1998–00 |
| Arthur Numan | 5 | 1992–98 | 1994–98 |
| Erwin Koeman | 3 | 1979–82, 1990–94 | 1993–94 |
| Gerald Vanenburg | 4 | 1986–93 | 1992–93 |
| Eric Gerets | 2 | 1985–92 | 1987–92 |
| Ruud Gullit | 10 | 1985–87 | 1986–87 |
| Hallvar Thoresen | 9 | 1981–88 | 1983–86 |
| Jan van Beveren | 1 | 1970–83 | 1973–83 |
| Willy van der Kuijlen | 1964–81 | 1965–73 | |
| Roel Wiersma | 1954–65 | 1954–65 | |
| Berend Scholtens | 1937–55 | ||
| Sjef van Run | 1926–42 | ||
| Ad van Eerd | 1927–32 | 1928– |
Read more about this topic: PSV Eindhoven