Potassium Nitrate - Properties

Properties

Potassium nitrate has an orthorhombic crystal structure at room temperature, which transforms to a trigonal system at 129 °C. Upon heating to temperatures between 550 and 790 °C under an oxygen atmosphere, it loses oxygen and reaches a temperature dependent equilibrium with potassium nitrite:

2 KNO3 → 2 KNO2 + O2

Potassium nitrate is moderately soluble in water, but its solubility increases with temperature (see infobox). The aqueous solution is almost neutral, exhibiting pH 6.2 at 14 °C for a 10% solution of commercial powder. It is not very hygroscopic, absorbing about 0.03% water in 80% relative humidity over 50 days. It is insoluble in alcohol and is not poisonous; it can react explosively with reducing agents, but it is not explosive on its own.

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