Potassium Iodate - Chemical Properties

Chemical Properties

Potassium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents. It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid, for example:

HIO3 + KOH → KIO3 + H2O

It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide.

3 I2 + 6 KOH → KIO3 + 5 KI + 3 H2O

Or by fusing potassium iodide with potassium chlorate, bromate or perchlorate, the melt is extracted with water and potassium iodate is isolated from the solution by crystallization:

KI + KClO3 → KIO3 + KCl

Conditions/substances to avoid include: heat, shock, friction, combustible materials, reducing materials, aluminium, organic compounds, carbon, hydrogen peroxide and sulfides.

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