Method of Experimental Determination
The pzc is typically obtained by acid-base titrations of colloidal dispersions while monitoring the electrophoretic mobility of the particles and the pH of the suspension. Several titrations are required to distinguish pzc from iep, using different electrolytes (including varying the electrolyte ionic strength). Once satisfactory graphs are obtained (acid/base amount—pH, and pH—zeta potential), the pzc is established as the common intersection point (cip) of the lines. Therefore, pzc is also sometimes referred to as cip.
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