Role in Transition Metal Chemistry
For transition metals, oxidative reaction results in the decrease in the dn to a configuration with fewer electrons, often 2e fewer. Oxidative addition is favored for metals that are (i) basic and/or (ii) easily oxidized. Metals with a relatively low oxidation state often satisfy one of these requirements, but even high oxidation state metals undergo oxidative addition, as illustrated by the oxidation of Pt(II) with chlorine:
- 2− + Cl2 → 2−
In classical organometallic chemistry, the formal oxidation state of the metal and the electron count of the complex both increase by two. One-electron changes are also possible and in fact some oxidative addition reactions proceed via series of 1e changes. Although oxidative additions can occur with the insertion of a metal into many different substrates, oxidative additions are most commonly seen with H–H, H–X, and C–X bonds because these substrates are most relevant to commercial applications.
Oxidative addition requires that the metal complex have a vacant coordination site. For this reason, oxidative additions are common for four- and five-coordinate complexes.
Reductive elimination is the reverse of oxidative addition. Reductive elimination is favored when the newly formed X–Y bond is strong. For reductive elimination to occur the two groups (X and Y) should be mutually adjacent on the metal's coordination sphere. Reductive elimination is the key product-releasing step of several reactions that form C–H and C–C bonds.
Read more about this topic: Oxidative Addition
Famous quotes containing the words role in, role, transition, metal and/or chemistry:
“Always and everywhere children take an active role in the construction and acquisition of learning and understanding. To learn is a satisfying experience, but also, as the psychologist Nelson Goodman tells us, to understand is to experience desire, drama, and conquest.”
—Carolyn Edwards (20th century)
“The most puzzling thing about TV is the steady advance of the sponsor across the line that has always separated news from promotion, entertainment from merchandising. The advertiser has assumed the role of originator, and the performer has gradually been eased into the role of peddler.”
—E.B. (Elwyn Brooks)
“The most remarkable aspect of the transition we are living through is not so much the passage from want to affluence as the passage from labor to leisure.... Leisure contains the future, it is the new horizon.... The prospect then is one of unremitting labor to bequeath to future generations a chance of founding a society of leisure that will overcome the demands and compulsions of productive labor so that time may be devoted to creative activities or simply to pleasure and happiness.”
—Henri Lefebvre (b. 1901)
“There were metal detectors on the staff-room doors and Hernandez usually had a drawer full of push-daggers, nunchuks, stun-guns, knucks, boot-knives, and whatever else the detectors had picked up. Like Friday morning at a South Miami high school.”
—William Gibson (b. 1948)
“Science with its retorts would have put me to sleep; it was the opportunity to be ignorant that I improved. It suggested to me that there was something to be seen if one had eyes. It made a believer of me more than before. I believed that the woods were not tenantless, but choke-full of honest spirits as good as myself any day,—not an empty chamber, in which chemistry was left to work alone, but an inhabited house,—and for a few moments I enjoyed fellowship with them.”
—Henry David Thoreau (1817–1862)