Organotins - Preparation of Organotin Compounds

Preparation of Organotin Compounds

Organotin compounds can be synthesised by reaction of a Grignard reagent with tin halides for example tin tetrachloride. An example is the organic synthesis of tributyl-stannane:

The Wurtz-like coupling of alkyl sodium compounds with tin halides yield tetraorganotin compounds. Another method is an redistribution reaction of tin halides with organoaluminium compounds (AlR3). Triorganotin halides can be prepared in the Kocheshkov redistribution reaction.

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