Concentration Dependent "collective" Diffusion
Collective diffusion is the diffusion of a large number of particles, most often within a solvent.
Contrary to brownian motion, which is the diffusion of a single particle, interactions between particles may have to be considered, unless the particles form an ideal mix with their solvent (ideal mix conditions correspond to the case where the interactions between the solvent and particles are identical to the interactions between particles and the interactions between solvent molecules; in this case, the particles do not interact when inside the solvent).
In case of an ideal mix, the particle diffusion equation holds true and the diffusion coefficient D the speed of diffusion in the particle diffusion equation is independent of particle concentration. In other cases, resulting interactions between particles within the solvent will account for the following effects:
- the diffusion coefficient D in the particle diffusion equation becomes dependent of concentration. For an attractive interaction between particles, the diffusion coefficient tends to decrease as concentration increases. For a repulsive interaction between particles, the diffusion coefficient tends to increase as concentration increases.
- In the case of an attractive interaction between particles, particles exhibit a tendency to coalesce and form clusters if their concentration lies above a certain threshold. This is equivalent to a precipitation chemical reaction (and if the considered diffusing particles are chemical molecules in solution, then it is a precipitation).
Read more about this topic: Molecular Diffusion
Famous quotes containing the words dependent and/or collective:
“The mother whose self-image is dependent on her children places on those children the responsibility for her own identity, and her involvement in the details of their lives can put great pressure on the children. A child suffers when everything he or she does is extremely important to a parent; this kind of over-involvement can turn even a small problem into a crisis.”
—Grace Baruch (20th century)
“We attempt to remember our collective American childhood, the way it was, but what we often remember is a combination of real past, pieces reshaped by bitterness and love, and, of course, the video past—the portrayals of family life on such television programs as “Leave it to Beaver” and “Father Knows Best” and all the rest.”
—Richard Louv (20th century)