Angle Changes
The pairs often exhibit a negative polar character with their high charge density and are located closer to the atomic nucleus on average compared to the bonding pair of electrons. The presence of a lone pair decreases the bond angle between the bonding pair of electrons, due to their high electric charge which causes great repulsion between the electrons. They are also used in the formation of a dative bond. For example, the creation of the hydronium (H3O+) ion occurs when acids are dissolved in water and is due to the oxygen atom donating a lone pair to the hydrogen ion.
This can be seen more clearly when looked at in two more common molecules. For example, in carbon dioxide (CO2), the oxygen atoms are on opposite sides of the carbon, whereas in water (H2O) there is an angle between the hydrogen atoms of 104.5ยบ. Due to the repulsive force of the oxygen atom's lone pairs, the hydrogens are pushed further away, to a point where the forces of all electrons on the hydrogen atom are in equilibrium. This is an illustration of the VSEPR theory.
Read more about this topic: Lone Pair
Famous quotes containing the word angle:
“So much symmetry!
Like the pale angle of time
And eternity.
The great shape labored and fell.”
—N. Scott Momaday (b. 1934)
“It is a mistake, to think the same thing affects both sight and touch. If the same angle or square, which is the object of touch, be also the object of vision, what should hinder the blind man, at first sight, from knowing it?”
—George Berkeley (1685–1753)