Free Electron Model - Fermi Level

Fermi Level

According to the Pauli principle, the electrons in the ground state occupy all the lowest-energy states, up to some Fermi energy . Since the energy is given by

,

this corresponds to occupying all the states with wave vectors, where is so-called Fermi wave vector, given by

,

where is the total number of electrons in the system, and V is the total volume. The Fermi energy is then

In a nearly-free-electron model of a -valent metal, one can replace with, where is the total number of metal ions.

Read more about this topic:  Free Electron Model

Famous quotes containing the word level:

    The truth is, that common-sense, or thought as it first emerges above the level of the narrowly practical, is deeply imbued with that bad logical quality to which the epithet metaphysical is commonly applied; and nothing can clear it up but a severe course of logic.
    Charles Sanders Peirce (1839–1914)