- Albania - Leon Menkshi
- Andorra - Marian van de Wal (singer for Andorra in 2005)
- Armenia - Sirusho (singer for Armenia in 2008)
- Austria - Eva Pölzl
- Belarus - Juliana
- Belgium - Maureen Louys (host of the Junior Eurovision Song Contest 2005)
- Bosnia and Herzegovina - Vesna Andree Zaimović
- Bulgaria - Mira Dobreva
- Croatia - Barbara Kolar
- Cyprus - Giannis Haralambous
- Czech Republic - Andrea Savane
- Denmark - Susanne Georgi (singer for Andorra in 2009)
- Estonia - Laura Põldvere (singer for Estonia in 2005 as part of the group, Suntribe)
- Finland - Laura Voutilainen (singer for Finland in 2002)
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- France - Vanessa Dolmen
- Georgia - Neli Agirba
- Germany - Thomas Hermanns
- Greece - Alexis Kostalas
- Hungary - Éva Novodomszky
- Iceland - Ragnhildur Steinunn Jónsdóttir
- Ireland - Linda Martin (singer for Ireland in 1984 and winner in 1992)
- Israel - Jason Danino-Holt
- Latvia - Janis Šipkevics
- Lithuania - Lavija Šurnaitė
- Macedonia - Elena Risteska (singer for Macedonia in 2006)
- Malta - Mireille Bonello
- Moldova - Andrei Porubin
- Montenegro - Vidak Latković
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- Netherlands - Paul de Leeuw and Edsilia Rombley
- Norway - Synnøve Svabø
- Poland - Maciej Orłoś
- Portugal - Francisco Mendes
- Romania - Andreea Marin Bănică
- Russia - Yana Churikova
- Serbia - Maja Nikolić
- Slovenia - Peter Poles
- Spain - Ainhoa Arbizu
- Sweden - André Pops
- Switzerland - Sven Epiney
- Turkey - Meltem Ersan Yazgan
- Ukraine - Katya Osadchaya
- United Kingdom - Fearne Cotton
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