Doppler Broadening

In atomic physics, Doppler broadening is the broadening of spectral lines due to the Doppler effect caused by a distribution of velocities of atoms or molecules. Different velocities of the emitting particles result in different (Doppler) shifts, the cumulative effect of which is the line broadening. The resulting line profile is known as a Doppler profile. A particular and perhaps the most important case is the thermal Doppler broadening due to the thermal motion of the particles. Then, the broadening depends only on the frequency of the spectral line, the mass of the emitting particles, and their temperature, and therefore can be used for inferring the temperature of an emitting body.

Saturated absorption spectroscopy, also known as Doppler-free spectroscopy, can be used to find the true frequency of an atomic transition without cooling a sample down to temperatures at which the Doppler broadening is minimal.