Coordination Complex - History

History

Coordination complexes were known – although not understood in any sense – since the beginning of chemistry, e.g. Prussian blue and copper vitriol. The key breakthrough occurred when Alfred Werner proposed in 1893 that Co(III) bears six ligands in an octahedral geometry. His theory allows one to understand the difference between coordinated and ionic in a compound, for example chloride in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers.

In 1914, Werner resolved the first coordination complex, called hexol, into optical isomers, overthrowing the theory that only carbon compounds could possess chirality.

Read more about this topic:  Coordination Complex

Famous quotes containing the word history:

    For a transitory enchanted moment man must have held his breath in the presence of this continent, compelled into an aesthetic contemplation he neither understood nor desired, face to face for the last time in history with something commensurate to his capacity for wonder.
    F. Scott Fitzgerald (1896–1940)

    What is most interesting and valuable in it, however, is not the materials for the history of Pontiac, or Braddock, or the Northwest, which it furnishes; not the annals of the country, but the natural facts, or perennials, which are ever without date. When out of history the truth shall be extracted, it will have shed its dates like withered leaves.
    Henry David Thoreau (1817–1862)

    The history of reform is always identical; it is the comparison of the idea with the fact. Our modes of living are not agreeable to our imagination. We suspect they are unworthy. We arraign our daily employments.
    Ralph Waldo Emerson (1803–1882)