Boiling Point
Brake fluid is subjected to very high temperatures, especially in the wheel cylinders of drum brakes and disk brake calipers. It must have a high boiling point to avoid vaporizing in the lines. This vaporization is a problem because vapor is compressible and negates hydraulic fluid transfer of braking force.
Quality standards refer to a brake fluid's "dry" and "wet" boiling points. Wet boiling point, which is usually much lower (although above most normal service temperatures), refers to the fluid's boiling point after absorbing a certain amount of moisture. This is several (single digit) percent, varying from formulation to formulation. Glycol-ether (DOT 3, 4, and 5.1) brake fluids are hygroscopic (water absorbing), which means they absorb moisture from the atmosphere under normal humidity levels. Non-hygroscopic fluids (e.g. silicone/DOT 5-based formulations), are hydrophobic, and can maintain an acceptable boiling point over the fluid's service life, although at the cost of potential phase separation/water pooling and freezing/boiling in the system over time - the main reason single phase hygroscopic fluids are used.
| Dry boiling point | Wet boiling point | |
|---|---|---|
| DOT 3 | 205 °C (401 °F) | 140 °C (284 °F) |
| DOT 4 | 230 °C (446 °F) | 155 °C (311 °F)
|
| DOT 5 | 260 °C (500 °F) | 180 °C (356 °F) |
| DOT 5.1 | 270 °C (518 °F) | 190 °C (374 °F) |
Wet boiling point defined as 3.7% water by volume.
Read more about this topic: Brake Fluid, Characteristics
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