Bond Strength

In chemistry, bond strength is the degree to which each atom joined to another in a chemical bond contributes to the valency of this other atom. Bond strength is intimately linked to bond order and can be quantified by:

  • bond energy: requires lengthy calculations, even for the simplest bonds.
  • bond-dissociation energy

Another criterion of bond strength is the qualitative relation between bond energies and the overlap of atomic orbitals of the bonds (Pauling and Mulliken). The more these overlap, the more the bonding electrons are to be found between the nuclei and hence stronger will be the bond. Overlap is necessary for the formation of molecular orbitals. This overlap can be calculated and is called the overlap integral.

Famous quotes containing the words bond and/or strength:

    The bond between a man and his profession is similar to that which ties him to his country; it is just as complex, often ambivalent, and in general it is understood completely only when it is broken: by exile or emigration in the case of one’s country, by retirement in the case of a trade or profession.
    Primo Levi (1919–1987)

    With a balanced combination of the two principal energies from mother and father, a girl can both be in touch with her womanly strengths and be a powerful force in the world—strong and nurturing, decisive and caring, goal- oriented and aware of the needs of others. She has the courage to voice what she thinks and feels and the strength to follow her destiny.
    Jeanne Elium (20th century)