Bond Strength

In chemistry, bond strength is the degree to which each atom joined to another in a chemical bond contributes to the valency of this other atom. Bond strength is intimately linked to bond order and can be quantified by:

  • bond energy: requires lengthy calculations, even for the simplest bonds.
  • bond-dissociation energy

Another criterion of bond strength is the qualitative relation between bond energies and the overlap of atomic orbitals of the bonds (Pauling and Mulliken). The more these overlap, the more the bonding electrons are to be found between the nuclei and hence stronger will be the bond. Overlap is necessary for the formation of molecular orbitals. This overlap can be calculated and is called the overlap integral.

Famous quotes containing the words bond and/or strength:

    I made no vows, but vows
    Were then made for me; bond unknown to me
    Was given, that I should be, else sinning greatly,
    A dedicated Spirit.
    William Wordsworth (1770–1850)

    Teach us to live our lives with purpose and with power
    for visions of a better world and for decision’s hour;
    To choose the way of life, reject the way of death,
    until the radiant force of God fills mind and strength and breath.
    Walter J. Mathams (19th–20th centuries)