In chemistry, bond strength is the degree to which each atom joined to another in a chemical bond contributes to the valency of this other atom. Bond strength is intimately linked to bond order and can be quantified by:
- bond energy: requires lengthy calculations, even for the simplest bonds.
- bond-dissociation energy
Another criterion of bond strength is the qualitative relation between bond energies and the overlap of atomic orbitals of the bonds (Pauling and Mulliken). The more these overlap, the more the bonding electrons are to be found between the nuclei and hence stronger will be the bond. Overlap is necessary for the formation of molecular orbitals. This overlap can be calculated and is called the overlap integral.
Famous quotes containing the words bond and/or strength:
“Man’s characteristic privilege is that the bond he accepts is not physical but moral; that is, social. He is governed not by a material environment brutally imposed on him, but by a conscience superior to his own, the superiority of which he feels. Because the greater, better part of his existence transcends the body, he escapes the body’s yoke, but is subject to that of society.”
—Emile Durkheim (1858–1917)
“Fearlessness is a more than ordinary strength of mind, which raises the soul above the troubles, disorders, and emotions which the prospect of great dangers are used to produce. And by this inward strength it is that heroes preserve themselves in a calm and quiet state, and enjoy a presence of mind and the free use of their reason in the midst of those terrible accidents that amaze and confound other people.”
—François, Duc De La Rochefoucauld (1613–1680)