Concrete
Carbonatation is a slow process that occurs in concrete where lime (calcium hydroxide) in the cement reacts with carbon dioxide from the air and forms calcium carbonate.
The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5. This highly alkaline environment is one in which the steel rebar is passivated and is protected from corrosion. According to the Pourbaix diagram for iron, the metal is passive when the pH is above 9.5.
The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made. This carbonatation process will start at the surface, then slowly move deeper and deeper into the concrete. The rate of carbonatation is dependent on the relative humidity of the concrete - a 50% relative humidity being optimal. If the object is cracked, the carbon dioxide in the air will be better able to penetrate into the concrete.
Eventually this may lead to corrosion of the rebar and damage to the construction.
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Famous quotes containing the word concrete:
““The city’s grotesque iron skeletons
Would knock their drunken penthouse heads together
And cake their concrete dirt off in the streets.””
—Robert Frost (1874–1963)
“A doctor, like anyone else who has to deal with human beings, each of them unique, cannot be a scientist; he is either, like the surgeon, a craftsman, or, like the physician and the psychologist, an artist.... This means that in order to be a good doctor a man must also have a good character, that is to say, whatever weaknesses and foibles he may have, he must love his fellow human beings in the concrete and desire their good before his own.”
—W.H. (Wystan Hugh)
“We are all hungry and thirsty for concrete images. Abstract art will have been good for one thing: to restore its exact virginity to figurative art.”
—Salvador Dali (1904–1989)