Kroll Process
ZrCl4 is an intermediate in the conversion of zirconium minerals to metallic zirconium by the Kroll process. In nature, zirconium minerals invariably exist as oxides (reflected also by the tendency of all zirconium chlorides to hydrolyze). For their conversion to bulk metal, these refractory oxides are first converted to the tetrachloride, which can be distilled at high temperatures. This conversion entails treatment of the oxide with carbon as the oxide "getter" and chlorine.
- ZrO2 + 2 C + 2 Cl2 → ZrCl4 + 2 CO
For a simpler procedure see: Inorg. Syn., 4, 121-126(1953).
Read more about this topic: Zirconium(IV) Chloride
Famous quotes containing the word process:
“... geometry became a symbol for human relations, except that it was better, because in geometry things never go bad. If certain things occur, if certain lines meet, an angle is born. You cannot fail. It’s not going to fail; it is eternal. I found in rules of mathematics a peace and a trust that I could not place in human beings. This sublimation was total and remained total. Thus, I’m able to avoid or manipulate or process pain.”
—Louise Bourgeois (b. 1911)