- Lyudmila Savelyeva as Natasha Rostova
- Oleg Tabakov as Nikolai Rostov
- Sergei Yermilov as Petya Rostov
- Viktor Stanitsyn as Ilya Rostov
- Kira Golovko as Natalya Rostova
- Irina Gubanova as Sonya Rostova
- Edvard Martsevich as Boris Drubetskoy
- Aleksandr Borisov as "Uncle" Rostov
- Nikolai Rybnikov as Vasily Denisov
- Viktor Murganov as Alexander I of Russia
- Larisa Borisenko as Mlle. Bourienne
- Georgy Millyar as Morel
- Jean-Claude Ballard as Ramballe
- Nonna Mordyukova as Anisya
- Anna Timiryova as old lady
- Boris Khmelnitsky as Bolkonsky's adjutant
- Valeri Yeremichev as Alexander Ostermann-Tolstoy
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- Sergei Bondarchuk as Pierre Bezukhov
- Irina Skobtseva as Hélène Kuragin
- Vasili Lanovoy as Anatol Kuragin
- Oleg Yefremov as Fedor Dolokhov
- Boris Smirnov as Vasili Kuragin
- Nikolai Tolkachev as Kyril Bezukhov
- Dzhemma Firsova as Katishe Mamontova
- Mikhail Khrabrov as Platon Karataev
- Nikolai Trofimov as Tushin
- Vladislav Strzhelchik as Napoleon
- Jānis Grantiņš as Ludwig von Wolzogen
- Dz. Eizentāls as Carl von Clausewitz
- Galina Kravchenko as Marya Karagina
- Boris Molchanov as Louis-Nicolas Davout
- Lev Polyakov as Jacques Lauriston
- Rodion Aleksandrov as Alexander Balashov
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- Vyacheslav Tikhonov as Andrei Bolkonsky
- Anatoli Ktorov as Nikolai Bolkonsky
- Anastasiya Vertinskaya as Lisa Bolkonskaya
- Antonina Shuranova as Maria Bolkonskaya
- Boris Zakhava as Mikhail Kutuzov
- Nikita Mikhalkov as Russian soldier
- Giuli Chokhonelidze as Pyotr Bagration
- Vadim Safronov as Francis II
- Yelena Tyapkina as Akhrosimova
- Herberts Zommers as Count Benningsen
- Nikolai Bubnov as Karl Mack von Leiberich
- Angelina Stepanova as Anna Scherer
- Erwin Knausmüller as Franz von Weyrother
- Mikhail Pogorzhelsky as Michael Andreas Barclay de Tolly
- Leonid Vidavsky as Paisi Kaysarov
- Nikolai Grinko as Dessalles
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