Vinyl Chloride - Fire and Explosion Hazard

Fire and Explosion Hazard

OSHA lists VCM as a Class IA Flammable Liquid, with an National Fire Protection Association Flammability Rating of 4. Because of its low boiling point, liquid VCM will undergo flash evaporation (i.e., autorefrigerate) upon its release to atmospheric pressure. The portion vaporized will form a dense cloud (more than twice as heavy as the surrounding air). The risk of subsequent explosion or fire is significant. According to OSHA, the flash point of VCM is -78 C (-108 F). Its flammable limits in air are: lower 3.6 volume % and upper 33.0 volume %. Fire may release toxic hydrogen chloride (HCl) and carbon monoxide (CO).

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