Marquisses of Villafranca Del Bierzo
- 1st Luis Pimentel y Pacego
- 2nd Pedro Álvarez de Toledo
- 3rd Fadrique Álvarez de Toledo y Osorio; no issue
- 4th García Álvarez de Toledo
- 5th Pedro Álvarez de Toledo
- 6th García Álvarez de Toledo; no Issue; brother of Fadrique Álvarez de Toledo y Mendoza
- 7th Fadrique Álvarez de Toledo y Ponce de León; son of Mendoza
- 9th Fadrique Vicente Álvarez de Toledo; married sister of 13th Duke of Medina Sidonia
- 10th Antonio Álvarez de Toledo y Pérez de Guzmán
- 11th José María Álvarez de Toledo (15th Duke of Medina Sidonia)
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