Reactions
Consistent with its high oxidizing power, VCl4 reacts with HBr at -50 °C to produce VBr3. The reaction proceeds via VBr4, which releases Br2 during warming to room temperature.
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- 2 VCl4 + 8 HBr → 2 VBr3 + 8 HCl + Br2
VCl4 forms adducts with many donor ligands, for example, VCl4(THF)2.
It is the precursor to vanadocene dichloride.
Read more about this topic: Vanadium Tetrachloride
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