"Maximum Number of Bonds" Definition
The International Union of Pure and Applied Chemistry (IUPAC) has made several attempts to arrive at an unambiguous definition of valence. The current version, adopted in 1994,:
- The maximum number of univalent atoms (originally hydrogen or chlorine atoms) that may combine with an atom of the element under consideration, or with a fragment, or for which an atom of this element can be substituted.
Hydrogen and chlorine were originally used as examples of univalent atoms, because of their nature to form only one single bond. Hydrogen has only one valence electron and can form only one bond with an atom that has an incomplete outer shell. Chlorine has seven valence electrons and can form only one bond with an atom that donates a valence electron to complete chlorine's outer shell. However, chlorine can also have oxidation states from +1 to +7 and can form more than one bond by donating valence electrons.
Although hydrogen has only one valence electron, it can form bonds with more than one atom in hypervalent bonds. In the bifluoride ion (−), for example, it forms a three-center four-electron bond with two fluoride atoms:
Another example is the Three-center two-electron bond in diborane (B2H6).
Read more about this topic: Valence (chemistry)
Famous quotes containing the words maximum, number, bonds and/or definition:
“Only at his maximum does an individual surpass all his derivative elements, and become purely himself. And most people never get there. In his own pure individuality a man surpasses his father and mother, and is utterly unknown to them.”
—D.H. (David Herbert)
“There is not to be found, in all history, any miracle attested by a sufficient number of men, of such unquestioned good sense, education, and learning, as to secure us against all delusion in themselves ... beyond all suspicion of any design to deceive others ... and at the same time attesting facts, performed in such a public manner, and in so celebrated a part of the world, as to render the detection unavoidable.”
—David Hume (1711–1776)
“In America a woman loses her independence for ever in the bonds of matrimony. While there is less constraint on girls there than anywhere else, a wife submits to stricter obligations. For the former, her father’s house is a home of freedom and pleasure; for the latter, her husband’s is almost a cloister.”
—Alexis de Tocqueville (1805–1859)
“Scientific method is the way to truth, but it affords, even in
principle, no unique definition of truth. Any so-called pragmatic
definition of truth is doomed to failure equally.”
—Willard Van Orman Quine (b. 1908)