Contestants
| Year | Artist | Title | Final | Points | Semi | Points |
|---|---|---|---|---|---|---|
| 2003 | Oleksandr Ponomaryov | "Hasta la Vista" | 14 | 30 | ||
| 2004 | Ruslana | "Wild Dances" | 1 | 280 | 2 | 256 |
| 2005 | GreenJolly | "Razom nas bahato" (Разом нас багато) | 19 | 30 | X | X |
| 2006 | Tina Karol | "Show Me Your Love" | 7 | 145 | 7 | 146 |
| 2007 | Verka Serduchka | "Dancing Lasha Tumbai" | 2 | 235 | X | X |
| 2008 | Ani Lorak | "Shady Lady" | 2 | 230 | 1 | 152 |
| 2009 | Svetlana Loboda | "Be My Valentine! (Anti-Crisis Girl)" | 12 | 76 | 6 | 80 |
| 2010 | Alyosha | "Sweet People" | 10 | 108 | 7 | 77 |
| 2011 | Mika Newton | "Angel" | 4 | 159 | 6 | 81 |
| 2012 | Gaitana | "Be My Guest" | 15 | 65 | 8 | 64 |
| 2013 |
- XX on Semi Finals denotes auto-qualification. This could be due to two reasons. If a country won the previous year, they did not have to compete in Semi Finals, or back in the early 2005-2007 era, countries who done well did not have to compete in Semi Finals the following year. The top ten non-Big four along with the Big four countries automatically qualified, for example, if Germany and France placed inside the top 10, the 11th and 12th spots were advanced to next year's Grand Final along with everyone within the top 10.
- XX on Finals denotes an unsuccessful attempt to qualify to the final.
- In 2012, Cyprus and Ukraine were both awarded with 65 points each in the Final, however, as regulated by the "count-back" tie-breaker rule, Ukraine finished 15th overall and Cyprus 16th because Ukraine received points from more countries in the Final than Cyprus.
Read more about this topic: Ukraine In The Eurovision Song Contest