Theory
Transmission Raman is possible because light scatters through turbid materials that do not significantly absorb or block the light. In a similar mechanism to Spatially Offset Raman Spectroscopy, the light in a diffusely scattering sample spreads through the object randomly (Transmission Raman can be regarded as an extreme example of SORS). As Raman photons can be created at all points that the light passes through the total scrambled Raman signal measured on the opposite face of the object is highly representative of the bulk of the material. This desirable property removes a problem with conventional, widely used back-scattering Raman spectroscopy where the signal tends to be representative of the surface and near-surface composition. Because Raman does not rely on absorption and the light spreads throughout the sample, a large thickness can be measured in the absence of photon absorption. This produces an analysis representative of the entire mixture and is typically insensitive to coatings, or thin containers.
Read more about this topic: Transmission Raman Spectroscopy
Famous quotes containing the word theory:
“every subjective phenomenon is essentially connected with a single point of view, and it seems inevitable that an objective, physical theory will abandon that point of view.”
—Thomas Nagel (b. 1938)
“Many people have an oversimplified picture of bonding that could be called the “epoxy” theory of relationships...if you don’t get properly “glued” to your babies at exactly the right time, which only occurs very soon after birth, then you will have missed your chance.”
—Pamela Patrick Novotny (20th century)
“We have our little theory on all human and divine things. Poetry, the workings of genius itself, which, in all times, with one or another meaning, has been called Inspiration, and held to be mysterious and inscrutable, is no longer without its scientific exposition. The building of the lofty rhyme is like any other masonry or bricklaying: we have theories of its rise, height, decline and fall—which latter, it would seem, is now near, among all people.”
—Thomas Carlyle (1795–1881)