Total Organic Carbon - Analyzers

Analyzers

Virtually all TOC analyzers measure the CO₂ formed when organic carbon is oxidized and/or when inorganic carbon is acidified. Oxidation is performed either through Pt-catalyzed combustion, by heated persulfate, or with a UV/persulfate reactor. Once the CO₂ is formed, it is measured by a detector: either a conductivity cell (if the CO₂ is aqueous) or a non-dispersive infrared cell (after purging the aqueous CO₂ into the gaseous phase). Conductivity detection is only desirable in the lower TOC ranges in deionized waters, whereas NDIR detection excels in all TOC ranges. A variation described as Membrane Conductivity Detection can allow for measurement of TOC across a wide analytical range in both deionized and non-deionized water samples. Modern high-performance TOC instruments are capable of detecting carbon concentrations well below 1 µg/L (1 part per billion or ppb).

A total organic carbon analyzer determines the amount of carbon in a water sample. By acidifying the sample and flushing with nitrogen or helium the sample removes inorganic carbon, leaving only organic carbon sources for measurement. There are two types of analyzers. One uses combustion and the other chemical oxidation. This is used as a water purity test, as the presence of bacteria introduces organic carbon.