Sulfur Tetrafluoride - Synthesis and Manufacture

Synthesis and Manufacture

SF4 is produced by the reaction of SCl2, Cl2, and NaF:

SCl2 + Cl2 + 4 NaF → SF4 + 4 NaCl

Treatment of SCl2 with NaF also affords SF4, not SF2. SF2 is unstable, it condenses with itself to form SF4 and SSF2.

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