Sulfur Tetrafluoride - Other Reactions

Other Reactions

Sulfur chloride pentafluoride (SF5Cl), a useful source of the SF5 group, is prepared from SF4.

Hydrolysis of SF4 gives sulfur dioxide:

SF4 + 2 H2O → SO2 + 4 HF

This reaction proceeds via the intermediacy of thionyl fluoride, which usually does not interfere with the use of SF4 as a reagent.

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