Strain (chemistry)

In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound. The internal energy of a molecule consists of all the energy stored within it. A strained molecule has an additional amount of internal energy which an unstrained molecule does not. This extra internal energy, or strain energy, can be likened to a compressed spring. Much like a compressed spring must be held in place to prevent release of its potential energy, a molecule can be held in an energetically unfavorable conformation by the bonds within that molecule. Without the bonds holding the conformation in place, the strain energy would be released.

Famous quotes containing the word strain:

    Realistic about how much one person can accomplish in a given day, women expect to have to make some trade-offs between work and family. Families, however, have absorbed all the stress and strain they possibly can. The entire responsibility for accommodation is taking place on the home side of the equation.
    Deborah J. Swiss (20th century)