Spectral Theory - Physical Background

Physical Background

The background in the physics of vibrations has been explained in this way:

Spectral theory is connected with the investigation of localized vibrations of a variety of different objects, from atoms and molecules in chemistry to obstacles in acoustic waveguides. These vibrations have frequencies, and the issue is to decide when such localized vibrations occur, and how to go about computing the frequencies. This is a very complicated problem since every object has not only a fundamental tone but also a complicated series of overtones, which vary radically from one body to another.

The mathematical theory is not dependent on such physical ideas on a technical level, but there are examples of mutual influence (see for example Mark Kac's question Can you hear the shape of a drum?). Hilbert's adoption of the term "spectrum" has been attributed to an 1897 paper of Wilhelm Wirtinger on Hill differential equation (by Jean Dieudonné), and it was taken up by his students during the first decade of the twentieth century, among them Erhard Schmidt and Hermann Weyl. The conceptual basis for Hilbert space was developed from Hilbert's ideas by Erhard Schmidt and Frigyes Riesz. It was almost twenty years later, when quantum mechanics was formulated in terms of the Schrödinger equation, that the connection was made to atomic spectra; a connection with the mathematical physics of vibration had been suspected before, as remarked by Henri Poincaré, but rejected for simple quantitative reasons, absent an explanation of the Balmer series. The later discovery in quantum mechanics that spectral theory could explain features of atomic spectra was therefore fortuitous, rather than being an object of Hilbert's spectral theory.

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