Sodium Bromide - Synthesis, Structure, Reactions

Synthesis, Structure, Reactions

NaBr crystallizes in the same cubic motif as NaCl, NaF and NaI. It is produced by treating sodium hydroxide with hydrogen bromide. The anhydrous salt crystallizes above 50.7 °C.

Br2 + 2NaOH → NaBr + NaBrO +H2O

Sodium bromide can be used as a source of the chemical element bromine. This can be accomplished by treating an aqueous solution of NaBr with chlorine gas:

2 NaBr + Cl2 → Br2 + 2 NaCl

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