SN2 Reaction - Roundabout Mechanism

A development attracting attention in 2008 concerns a SN2 roundabout mechanism observed in a gas-phase reaction between chloride ions and methyl iodide with a special technique called crossed molecular beam imaging. When the chloride ions have sufficient velocity, the energy of the resulting iodide ions after the collision is much lower than expected, and it is theorized that energy is lost as a result of a full roundabout of the methyl group around the iodine atom before the actual displacement takes place.

Read more about this topic:  SN2 Reaction

Famous quotes containing the words roundabout and/or mechanism:

    Life is a long Dardenelles, My Dear Madam, the shores whereof are bright with flowers, which we want to pluck, but the bank is too high; & so we float on & on, hoping to come to a landing-place at last—but swoop! we launch into the great sea! Yet the geographers say, even then we must not despair, because across the great sea, however desolate & vacant it may look, lie all Persia & the delicious lands roundabout Damascus.
    Herman Melville (1819–1891)

    Life is an offensive, directed against the repetitious mechanism of the Universe.
    Alfred North Whitehead (1861–1947)