Seawater - Origin

Origin

Total Molar Composition of Seawater (Salinity = 35)
Component Concentration (mol/kg)
H2O 53.6
Cl− 0.546
Na+ 0.469
Mg2+ 0.0528
SO2−
4
0.0282
Ca2+ 0.0103
K+ 0.0102
CT 0.00206
Br− 0.000844
BT 0.000416
Sr2+ 0.000091
F− 0.000068

Scientific theories behind the origins of sea salt started with Sir Edmond Halley in 1715, who proposed that salt and other minerals were carried into the sea by rivers after rainfall washed it out of the ground. Upon reaching the ocean, these salts concentrated as more salt arrived over time (see Hydrologic cycle.) Halley noted that most lakes that don’t have ocean outlets (such as the Dead Sea and the Caspian Sea, see endorheic basin), have high salt content. Halley termed this process "continental weathering".

Halley's theory was partly correct. In addition, sodium leached out of the ocean floor when the ocean formed. The presence of salt’s other dominant ion, chloride, results from outgassing of chloride (as hydrochloric acid) with other gases from Earth's interior via volcanos and hydrothermal vents. The sodium and chloride ions subsequently became the most abundant constituents of sea salt.

Ocean salinity has been stable for billions of years, most likely as a consequence of a chemical/tectonic system which removes as much salt as is deposited; for instance, sodium and chloride sinks include evaporite deposits, pore water burial, and reactions with seafloor basalts. Following the ocean's formation, sodium no longer leached from the ocean floor, but instead was captured in sedimentary layers covering the ocean bed. Plate tectonics possibly forces salt under the continental land masses, where it slowly leaches again to the surface.

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