Reverse Recovery Time
The most important difference between the p-n and Schottky diode is reverse recovery time, when the diode switches from conducting to non-conducting state. Where in a p-n diode the reverse recovery time can be in the order of hundreds of nanoseconds and less than 100 ns for fast diodes, Schottky diodes do not have a recovery time, as there is nothing to recover from (i.e. no charge carrier depletion region at the junction). The switching time is ~100 ps for the small signal diodes, and up to tens of nanoseconds for special high-capacity power diodes. With p-n junction switching, there is also a reverse recovery current, which in high-power semiconductors brings increased EMI noise. With Schottky diodes switching essentially instantly with only slight capacitive loading, this is much less of a concern.
It is often said that the Schottky diode is a "majority carrier" semiconductor device. This means that if the semiconductor body is doped n-type, only the n-type carriers (mobile electrons) play a significant role in normal operation of the device. The majority carriers are quickly injected into the conduction band of the metal contact on the other side of the diode to become free moving electrons. Therefore no slow, random recombination of n- and p- type carriers is involved, so that this diode can cease conduction faster than an ordinary p-n rectifier diode. This property in turn allows a smaller device area, which also makes for a faster transition. This is another reason why Schottky diodes are useful in switch-mode power converters; the high speed of the diode means that the circuit can operate at frequencies in the range 200 kHz to 2 MHz, allowing the use of small inductors and capacitors with greater efficiency than would be possible with other diode types. Small-area Schottky diodes are the heart of RF detectors and mixers, which often operate up to 50 GHz.
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