Applications
Because of its ability to harden platinum and palladium, ruthenium is used in platinum and palladium alloys to make wear-resistant electrical contacts. In this application, only thin plated films are used to achieve the necessary wear-resistance. Because of its lower cost and similar properties compared to rhodium, the use as plating material for electric contacts is one of the major applications. The thin coatings are either applied by electroplating or sputtering.
Ruthenium dioxide and lead and bismuth ruthenates are used in thick-film chip resistors. These two electronic applications account for 50% of the ruthenium consumption.
Only a few ruthenium alloys are used other than those with other platinum group metals. Ruthenium is often used in small quantities in those alloys to improve some of their properties. The beneficial effect on the corrosion resistance of titanium alloys led to the development of a special alloy containing 0.1% ruthenium. Ruthenium is also used in some advanced high-temperature single-crystal superalloys, with applications including the turbine blades in jet engines. Several nickel based superalloy compositions are described in the literature. Among them are EPM-102 (with 3% Ru) and TMS-162 (with 6% Ru), as well as TMS-138 and TMS-174. both containing 6% rhenium. Fountain pen nibs are frequently tipped with alloys containing ruthenium. From 1944 onward, the famous Parker 51 fountain pen was fitted with the "RU" nib, a 14K gold nib tipped with 96.2% ruthenium and 3.8% iridium.
Ruthenium is a component of mixed-metal oxide (MMO) anodes used for cathodic protection of underground and submerged structures, and for electrolytic cells for chemical processes such as generating chlorine from salt water. The fluorescence of some ruthenium complexes is quenched by oxygen, which has led to their use as optode sensors for oxygen. Ruthenium red, 6+, is a biological stain used to stain polyanionic molecules such as pectin and nucleic acids for light microscopy and electron microscopy. The beta-decaying isotope 106 of ruthenium is used in radiotherapy of eye tumors, mainly malignant melanomas of the uvea. Ruthenium-centered complexes are being researched for possible anticancer properties. Compared with platinum complexes, those of ruthenium show greater resistance to hydrolysis and more selective action on tumors. NAMI-A and KP1019 are two drugs undergoing clinical evaluation against metastatic tumors and colon cancers.
Read more about this topic: Ruthenium Compounds