Captains-General
- John Murray, 1st Marquess of Atholl c.1676–1703
- George Mackenzie, 1st Earl of Cromartie 1703–1714
- David Wemyss, 4th Earl of Wemyss 1715–1720
- vacant
- James Hamilton, 5th Duke of Hamilton 1724–1743
- James Wemyss, 5th Earl of Wemyss 1743–1756
- Charles Douglas, 3rd Duke of Queensberry 1756–1778
- Henry Scott, 3rd Duke of Buccleuch 1778–1812
- Charles Montagu-Scott, 4th Duke of Buccleuch 1812–1819
- John Hope, 4th Earl of Hopetoun 1819–1823
- James Graham, 3rd Duke of Montrose 1824–1830
- George Ramsay, 9th Earl of Dalhousie 1830–1838
- Walter Montagu-Douglas-Scott, 5th Duke of Buccleuch 1838–1884
- William Montagu-Douglas-Scott, 6th Duke of Buccleuch 1884–1914
- John Montagu-Douglas-Scott, 7th Duke of Buccleuch 1914–1935
- Sidney Buller-Fullerton-Elphinstone, 16th Lord Elphinstone 1935–1953
- John Dalrymple, 12th Earl of Stair 1953–1961
- Walter Montagu-Douglas-Scott, 8th Duke of Buccleuch 1961–1973
- John Dalrymple, 13th Earl of Stair 1973–1988
- Ronald Colville, 2nd Baron Clydesmuir 1988–1996
- Sir Hew Fleetwood Hamilton-Dalrymple, 10th Baronet 1996–2004
- David Ogilvy, 13th Earl of Airlie 2004–present
Read more about this topic: Royal Company Of Archers