Measurement of The Biomass Fraction of RDF and SRF
The biomass fraction of RDF and SRF has a monetary value under multiple greenhouse gas protocols, such as the European Union Emissions Trading Scheme and the Renewable Obligation Certificate program in the United Kingdom. Biomass is considered to be carbon-neutral since the CO2 liberated from the combustion of biomass is recycled in plants. The combusted biomass fraction of RDF/SRF is used by stationary combustion operators to reduce their overall reported CO2 emissions.
Several methods have been developed by the European CEN 343 working group to determine the biomass fraction of RDF/SRF. The initial two methods developed (CEN/TS 15440) were the manual sorting method and the selective dissolution method. Since each method suffered from limitations in properly characterizing the biomass fraction, an alternative method was developed using the principles of radiocarbon dating. A technical review (CEN/TR 15591:2007) outlining the carbon-14 method was published in 2007, and a technical standard of the carbon dating method (CEN/TS 15747:2008) was published in 2008. In the United States, there is already an equivalent carbon-14 method under the standard method ASTM D6866.
Although carbon-14 dating can determine with excellent precision the biomass fraction of RDF/SRF, it cannot determine directly the biomass calorific value. Determining the calorific value is important for green certificate programs such as the Renewable Obligation Certificate program in the United Kingdom. These programs award certificates based on the energy produced from biomass. Several research papers, including the one commissioned by the Renewable Energy Association in the UK, have been published that demonstrate how the carbon-14 result can be used to calculate the biomass calorific value.
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