Equilibrium Reactions or Opposed Reactions
A pair of forward and reverse reactions may define an equilibrium process. For example, A and B react into X and Y and vice versa (s, t, u, and v are the stoichiometric coefficients):
The reaction rate expression for the above reactions (assuming each one is elementary) can be expressed as:
where: k1 is the rate coefficient for the reaction that consumes A and B; k2 is the rate coefficient for the backwards reaction, which consumes X and Y and produces A and B.
The constants k1 and k2 are related to the equilibrium coefficient for the reaction (K) by the following relationship (set r=0 in balance):
Read more about this topic: Rate Equation
Famous quotes containing the words equilibrium, reactions and/or opposed:
“That doctrine [of peace at any price] has done more mischief than any I can well recall that have been afloat in this country. It has occasioned more wars than any of the most ruthless conquerors. It has disturbed and nearly destroyed that political equilibrium so necessary to the liberties and the welfare of the world.”
—Benjamin Disraeli (18041881)
“Separation anxiety is normal part of development, but individual reactions are partly explained by experience, that is, by how frequently children have been left in the care of others.... A mother who is never apart from her young child may be saying to him or her subliminally: You are only safe when Im with you.”
—Cathy Rindner Tempelsman (20th century)
“To offend and judge are distinct offices,
And of opposed natures.”
—William Shakespeare (15641616)