Reduction of Metal Compounds
In addition to the reduction of organic compounds by the solvated electrons it has been reported that upon irradiation a pertechnetate solution, at pH 4.1 is converted to a colloid of technetium dioxide. Irradiation of a solution at pH 1.8 soluble Tc(IV) complexes are formed. Irradiation of a solution at 2.7 forms a mixture of the colloid and the soluble Tc(IV) compounds. Gamma irradiation has been used in the synthesis of nanoparticles of gold on iron oxide (Fe2O3).
It has been shown that the irradiation of aqueous solutions of lead compounds leads to the formation of elemental lead, when an inorganic solid such as bentonite and sodium formate are present then the lead is removed from the aqueous solution.
Read more about this topic: Radiation Chemistry
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