Notable Alumnae
- Academic
- Angela Cummine - Rhodes Scholar (2007)
- Patricia Dyson - Educator; former Principal of the Presbyterian Ladies' College, Sydney (1978–1985)
- Entertainment, media and the arts
- Jenny Coupland - Miss Australia 1982
- Jacqueline McKenzie - Actress, Singer, Artist.
- Melissa Doyle - Co-host of the Seven Network breakfast television programme Sunrise
- Dame Joan Hammond - soprano, singing coach and golfer
- Amber Higlett - Finance Presenter/Reporter and Newsreader National Nine News
- Caroline Pemberton - Miss Australia 2007
- Sarah Song - Winner of Miss Sydney Chinese 2006 and Miss Chinese International 2007. She is currently working as an actress in TVB in Hong Kong.
- Sophie Wilcox - Anchor for Channel WT5-Idaho's "Shopping with Sophie" segment
- Polly Porter - Winner of The Block 2011 and television presenter and weather girl on Channel 9
- Paula Joye - Editor - Madison Magazine, Guest Judge - Project Runway Australia
- Politics, public service and the law
- Marie Byles -Female solicitor in NSW, Mountaineer, Explorer, Author and Feminist (also attended the Presbyterian Ladies' College, Sydney)
- Elizabeth Evatt, Judge of an Australian federal court
- Sport
- Sophie Ferguson - Professional Tennis Player
- Ellyse Perry - Australian Football team and member of Australian cricket team
- Edwina Tops-Alexander - Equestrian Athlete representative to 2012 London Olympics
- Ming Xiu Ong - Commonwealth Games Swimmer
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